It is demonstrated that the identity of the ligand labilized from the ligand field excited states of [Rh(NH3)5Cl]2+ is a function of the solvent medium, with Cl– substitution predominating in water and formamide solutions but NH3 substitution predominating in dimethylformamide, methanol, and dimethyl sulphoxide solutions.
M. A. Bergkamp, R. J. Watts and P. C. Ford, J. Chem. Soc., Chem. Commun., 1979, 623 DOI: 10.1039/C39790000623
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