The ratios of syn and anti N-chloroamines obtained from treatment of 7-azabenzonorbornenes and 7-azabenzonorbornadienes with N-chlorosuccinimide at –50°C vary with the electronic character of the substituents on the benzenoid ring and differ substantially from the ratios observed under conditions of rapid inversion at nitrogen.
J. R. Malpass and M. P. Walker, J. Chem. Soc., Chem. Commun., 1979, 585 DOI: 10.1039/C39790000585
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