At ambient temperature, an active species generated by the electroreduction of tungsten hexachloride with an aluminium anode catalyses the metathesis of internal olefins in halogenated solvents with good activity and selectivity.
M. Gilet, A. Mortreux, J. Nicole and F. Petit, J. Chem. Soc., Chem. Commun., 1979, 521 DOI: 10.1039/C39790000521
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