2-Arylazirines react with carbon monoxide and chlorodicarbonylrhodium(I) dimer, at room temperature or below, to give isocyanates (also ureas and carbamates by appropriate reaction) in good yields.
T. Sakakibara and H. Alper, J. Chem. Soc., Chem. Commun., 1979, 458 DOI: 10.1039/C39790000458
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