Absolute rate constants for addition of alkyl radicals (R·) to diethyl vinylphosphonate at 233 K increase in the order R = Me > Et > Pri > But, indicating the predominance of polar effects over steric or thermodynamic factors.
J. A. Baban and B. P. Roberts, J. Chem. Soc., Chem. Commun., 1979, 373 DOI: 10.1039/C39790000373
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