The first di(µ-S)-bridge between two metal atoms has been observed in the tetrathionaphthalene (naptho[1,8-cd]dithiole-4,5-dithiolato) complex (Ph3P)2-(CO)2Br2Ir2(C10H4S4) and rationalized in terms of electronic effects which prevail over the steric constraints.
B. Teo and P. A. Snyder-Robinson, J. Chem. Soc., Chem. Commun., 1979, 255 DOI: 10.1039/C39790000255
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