Issue 5, 1979

Photo-oxygenation of diphenyldiazomethane in the presence of phenyl trimethylsilyl ketone. Oxygen transfer from carbonyl oxide to the silyl ketone

Abstract

Dye-sensitized photo-oxygenation of diphenyldiazomethane in the presence of phenyl trimethylsilyl ketone produced trimethylsilyl benzoate by reaction of a carbonyl oxide with the silyl ketone accompanied by 1,2-rearrangement of the trimethylsilyl group, together with benzophenone.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 233-234

Photo-oxygenation of diphenyldiazomethane in the presence of phenyl trimethylsilyl ketone. Oxygen transfer from carbonyl oxide to the silyl ketone

A. Sekiguchi, Y. Kabe and W. Ando, J. Chem. Soc., Chem. Commun., 1979, 233 DOI: 10.1039/C39790000233

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