The anion [Co6(CO)16P]– has been obtained by reaction of PCl3 with Na[Co(CO)4]; the six metal atoms form four triangles linked in a chain surrounding a ‘semi-interstitial’ phosphide atom.
P. Chini, G. Ciani, S. Martinengo, A. Sironi, L. Longhetti and B. T. Heaton, J. Chem. Soc., Chem. Commun., 1979, 188 DOI: 10.1039/C39790000188
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