The first examples of tris(imino)thietans (2) have been prepared by treatment of arylsulphonyl isothiocyanates with t-butyl isonitrile; the structure of the NN′-di-t-butyl-N″-p-tolylsulphonyl derivative has been determined by X-ray crystallography.
G. L'Abbé, L. Huybrechts, J. Declercq, G. Germain and M. van Meerssche, J. Chem. Soc., Chem. Commun., 1979, 160 DOI: 10.1039/C39790000160
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