Experimental requirements for making 13C T1ρ measurements for studying dynamic processes in solution and the utility of these measurements are pointed out; the method is used to study internal reorientation of the CHO group of benzaldehyde and p-methoxybenzaldehyde, the measurements providing useful exchange rate data some 100–120 K above the coalescence temperature.
D. M. Doddrel, M. R. Bendall, P. F. Barron and D. T. Pegg, J. Chem. Soc., Chem. Commun., 1979, 77 DOI: 10.1039/C39790000077
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