A successful theoretical correlation is made of experimental data on the M–H bond stretching modes of µ2-bridged metal hydrides with the M–H–M interbond angle, based on the application of central or valence force field to the MHM unit.
M. W. Howard, U. A. Jayasooriya, S. F. A. Kettle, D. B. Powell and N. Sheppard, J. Chem. Soc., Chem. Commun., 1979, 18 DOI: 10.1039/C39790000018
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