The normal trans,trans conformation of the ion pairs of the 1,3-diphenylallyl and 1,3-diphenylbutenyl carbanions is converted into cis,trans by photolysis with white light. The kinetics of the reverse dark reaction have been studied; the rate of this process is much greater for the tight than for the loose ion pair.
H. M. Parkes and R. N. Young, J. Chem. Soc., Perkin Trans. 2, 1978, 249 DOI: 10.1039/P29780000249
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...