Classical trajectories of a system of I2 plus 22 inert gas atoms confined to a spherical volume reproduce the cage effect as measured experimentally. Analysis of the trajectories shows that the primary cage effect can be subdivided into three categories but there is no clear borderline between one of these (delayed primary) and the secondary cage effect.
J. N. Murrell, A. J. Stace and R. Dammel, J. Chem. Soc., Faraday Trans. 2, 1978, 74, 1532 DOI: 10.1039/F29787401532
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