The concept of a multiple intergral which represents equilibirum adsorption isotherms of multi-component gas mistures on energetically heterogeneous solid surfaces has been applied to describe the kinetics of monolayer adsorption. Using the multiple integral, the analystical expressions for kinetic isotherms and adsorption rates of gas mixtures on heterogeneous solid surfaces have been derived.
M. Jaroniec, J. Chem. Soc., Faraday Trans. 2, 1978, 74, 1292 DOI: 10.1039/F29787401292
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