Proton magnetic resonance measurements have been used to justify a proposed mechanism for the interaction of water with sulphuric acid, where the molar fraction of water is y⩽ 0.5. Three different statistical states of the proton are considered, expressed by the formulae H3O+, H3O+·HSO–4 and H3O+(H2SO4). The molarities of these species are given for the stated water concentration range.
G. Sioli, L. Giuffre and P. M. Spaziante, J. Chem. Soc., Faraday Trans. 1, 1978, 74, 2179 DOI: 10.1039/F19787402179
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