The use of a combination of analytical procedures shows that in the radiolysed alkali metal nitrates (i) substantial amounts of oxidising species other than NO–2 are formed: (ii) previous measurements considerably underestimate G–NO–3 and (iii) 77 K irradiated NaNO3 undergoes a rapid annealing process on warming to room temperature.
A model for the radiolytic processes is developed from the data.
D. Muhammad and A. G. Maddock, J. Chem. Soc., Faraday Trans. 1, 1978, 74, 919 DOI: 10.1039/F19787400919
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