The synthesis and spectroscopic characterization of cis-[Fe(CO)4(GeMeH2)2](1) are described. This compound is converted into [{Fe(CO)4(GeMeH)}](2) and GeMeH3 in the dark. However, its light-assisted reactions are more rapid and result in minor quantities of more condensed clusters.
A. Bonny and K. M. MacKay, J. Chem. Soc., Dalton Trans., 1978, 506 DOI: 10.1039/DT9780000506
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