Solvent effects on the discriminatory properties of the transient [Fe(CN)5]3– intermediate in the dissociative (D) substitution at the complex ions [Fe(CN)5L]3–(L = 3- or 4-cyanopyridine) are described. The solvents employed are methanol—, ethanol—, and t-butyl alcohol–water mixtures; in each case the incoming group is cyanide ion.
M. J. Blandamer, J. Burgess and R. I. Haines, J. Chem. Soc., Dalton Trans., 1978, 244 DOI: 10.1039/DT9780000244
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