Biosynthetic experiments with (R)- and (S)-N methylcoclaurines in Tiliacoraracemosa Colebr. established that tiliacorine has the (S) and (R) configuration at the asymmetric centres C(1) and C(1′), respectively, and tiliacorinine has the (SS) configuration at both asymmetric centres.
D. S. Bhakuni, A. N. Singh, S. Jain and R. S. Kapil, J. Chem. Soc., Chem. Commun., 1978, 226b DOI: 10.1039/C3978000226B
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