The Barton reaction–the photolysis of alkyl nitrites–has been used to determine the microviscosity of a micelle core using a reciprocal relationship found between the ratio of hydroxy-ketone to ketone formed and the macroviscosities of solvents in homogeneous solution.
K. Law and P. de Mayo, J. Chem. Soc., Chem. Commun., 1978, 1110 DOI: 10.1039/C39780001110
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