µ-Chloro binuclear rhodium(I) complexes trap the bidentate PIII–NIII tautomers of bicyclic phosphoranes containing a P–H bond to give monomeric rhodium(I) complexes, two of which [(5a) and (5b)] have been characterised by X-ray crystallography.
D. Bondoux, I. Tkatchenko, D. Houalla, R. Wolf, C. Pradat, J. Riess and B. F. Mentzen, J. Chem. Soc., Chem. Commun., 1978, 1022 DOI: 10.1039/C39780001022
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