Issue 23, 1978

Matrix isolated 1,2-oxathietan-4-one 2-oxide: a 2π+ 2π adduct of sulphur dioxide and keten

Abstract

U.v. irradiation of mixtures of SO2 and keten in argon or nitrogen matrices at 10–20 K gave an adduct, identified on the basis of its i.r. spectrum and photodecomposition to carbon dioxide, as 1,2-oxathietan-4-one 2-oxide (5).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 1020-1022

Matrix isolated 1,2-oxathietan-4-one 2-oxide: a 2π+ 2π adduct of sulphur dioxide and keten

I. R. Dunkin and J. G. MacDonald, J. Chem. Soc., Chem. Commun., 1978, 1020 DOI: 10.1039/C39780001020

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