Issue 22, 1978
From the journal:

Journal of the Chemical Society, Chemical Communications

Isolation of intermediates in the acid hydrolysis of [Pt(PPh3)2(O2)]; the X-ray structure of [Pt2(O2)(OH)(PPh3)4][ClO4]·2C6H6

Sumit Bhaduri,   Paul R. Raithby,   Camilo I. Zuccaro,   Michael B. Hursthouse,   Luigi Casella  and  Renato Ugo  

Abstract

The hydrolysis of [Pt(PPh3)2(O2)] with non-co-ordinating acids leads to the formation of [Pt2(O2)(OH)(PPh3)4][X](1)(X = ClO4, PF6, BF4, NO3), and then [Pt2(OH)2(PPh3)4][X]2(2), with a stepwise loss of H2O2; the structure of (1) has been confirmed by an X-ray analysis.

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Article information

DOI
https://doi.org/10.1039/C39780000991
Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 991-992

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Isolation of intermediates in the acid hydrolysis of [Pt(PPh3)2(O2)]; the X-ray structure of [Pt2(O2)(OH)(PPh3)4][ClO4]·2C6H6

S. Bhaduri, P. R. Raithby, C. I. Zuccaro, M. B. Hursthouse, L. Casella and R. Ugo, J. Chem. Soc., Chem. Commun., 1978, 991 DOI: 10.1039/C39780000991

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