Complete aromatic substitution of cyclometallated aromatic rings in a series of iridium triaryl phosphite complexes is found to occur rapidly with Cl2 in benzene: the structure of [IrCl2{P(OC6Cl3Me-o)(OC6H4Me-o)2}(pyridine)(PMe3)] has been elucidated by X-ray crystallography.
M. J. Nolte, E. Singleton and E. van der stok, J. Chem. Soc., Chem. Commun., 1978, 973 DOI: 10.1039/C39780000973
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