Reaction of B2H6 with the benzo-fused heteroaromatic compounds (1a–d) produces the boroles (2a–d)via a rearrangement in which BH3 adduct formation is the first step.
K. K. Knapp, P. C. Keller and J. V. Rund, J. Chem. Soc., Chem. Commun., 1978, 971 DOI: 10.1039/C39780000971
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