Issue 21, 1978

Rearrangements of cyclopropylmethyl and but-3-enyl cobaloximes

Abstract

[1-13C]-1-Cyclopropylmethyl(pyridine)cobaloxime (1b) rearranges (in CDCl3 at 310 K) to [4-13C]-but-3-enyl(pyridine)cobaloxime (2b); 1-methylbut-3-enyl(pyridine)cobaloxime (3) rearranges to 2-methylbut-3-enyl(pyridine)cobaloxime (4) under the catalytic influence of trifluoroacetic acid in CDCl3.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 954-956

Rearrangements of cyclopropylmethyl and but-3-enyl cobaloximes

M. P. Atkins, B. T. Golding and P. J. Sellars, J. Chem. Soc., Chem. Commun., 1978, 954 DOI: 10.1039/C39780000954

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