A novel series of metal–metal bonded RuII, mixed valence RuII/III, and RuIII complexes [Ru(C22H22N4)]2n+, of a dibenzotetra-aza[14]annulene ligand have been isolated and characterized which possess ground spin-triplet, spin-doublet, and singlet states, respectively.
L. F. Warren and V. L. Goedken, J. Chem. Soc., Chem. Commun., 1978, 909 DOI: 10.1039/C39780000909
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