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Issue 18, 1978
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Preparation of trans,trans,trans- and cis,cis,trans-perhydrophenalen-9-ols by application of the three-migration cyanoborate process to isomeric perhydro-9b-boraphenalenes: differences between the cyanoborate and carbonylation reactions

Abstract

Application of the three-migration cyanoborate process to cis,cis-perhydro-9b-boraphenalene gives trans,trans,trans-perhydrophenalen-9-ol, in contrast to carbonylation which gives the cis,cis,cis-isomer; cis-trans-perhydro-9b-boraphenalene gives cis,cis,trans-perhydro-phenalen-9-ol by either process.

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Article information


J. Chem. Soc., Chem. Commun., 1978, 805-806
Article type
Paper

Preparation of trans,trans,trans- and cis,cis,trans-perhydrophenalen-9-ols by application of the three-migration cyanoborate process to isomeric perhydro-9b-boraphenalenes: differences between the cyanoborate and carbonylation reactions

A. Pelter, P. J. Maddocks and K. Smith, J. Chem. Soc., Chem. Commun., 1978, 805
DOI: 10.1039/C39780000805

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