Methyl isocyanate adds with its C![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
N group to the PN group of 1,2λ5-azaphospholes and -azaphospholines; depending on the nature of the ring and the phosphorus substituents the bicyclic adducts are stable or redissociate in solution or/and decompose in a Wittig-type reaction.
A. Schmidpeter and T. von Criegern, J. Chem. Soc., Chem. Commun., 1978, 470 DOI: 10.1039/C39780000470
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