Aminolysis of (R)- or (S)-α-methyl[γ-2H]allyl (1) or α-n-pentyl[γ-2H]allyl (2) 2,6-dichlorobenzoates with (R)- or (S)-α-methylbenzylamine (3) favours syn over anti displacement by a factor of 1·4–1·8.
T. Oritani and K. H. Overton, J. Chem. Soc., Chem. Commun., 1978, 454 DOI: 10.1039/C39780000454
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