In a number of 1,4-addition reactions yielding chiral products through asymmetric catalysis the enantiomeric yield of products was found to be inversely proportional to the dielectric constant of the solvent.
H. Wynberg and B. Greijdanus, J. Chem. Soc., Chem. Commun., 1978, 427 DOI: 10.1039/C39780000427
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