Attachment of electrons to 5-halogenouracils in γ-irradiated or photolysed neutral organic and aqueous glasses produces σ*-radicals in bromo- and iodo-derivatives in addition to π*-anions, whereas in fluoro- and chloro-uracils, only π*-radicals are observed using e.s.r. spectroscopy.
H. Riederer, J. Hüttermann and M. C. R. Symons, J. Chem. Soc., Chem. Commun., 1978, 313 DOI: 10.1039/C39780000313
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