The nature and the isomeric distribution of the neutral products, obtained from the gas-phase attack of radiolytically formed Brønsted acids on selected vicinal halogeno-alcohols, provide direct evidence of an extensive gas-phase neighbouring group participation process involving the intermediacy of an O-protonated alkene oxide.
G. Angelini and M. Speranza, J. Chem. Soc., Chem. Commun., 1978, 213 DOI: 10.1039/C39780000213
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