Dehydration of the (3R)-hydroxyalkyl S-thioester (1) by yeast fatty acid synthetase to give the trans-2-enoyl derivative (2) occurs by means of a syn-elimination of the elements of water.
B. Sedgwick, C. Morris and S. J. French, J. Chem. Soc., Chem. Commun., 1978, 193 DOI: 10.1039/C39780000193
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