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Issue 12, 1978
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Preparation and molecular structure of [Ta{H2Al(OC2H4OMe)2}(Me2PC2H4PMe2)2]2, a co-ordinatively unsaturated aluminohydride adduct of tantalum(I)

Abstract

Reaction of TaCl2(Me2PC2H4PMe2)2 with Na[H2Al(OC2H4OMe)2] affords [Ta{H2Al(OC2H4OMe)2}(Me2PC2H4PMe2)2]2, a co-ordinatively unsaturated complex based on an approximately square-pyramidal P4Ta–µ-H2–Al group.

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Article information


J. Chem. Soc., Chem. Commun., 1978, 500-501
Article type
Paper

Preparation and molecular structure of [Ta{H2Al(OC2H4OMe)2}(Me2PC2H4PMe2)2]2, a co-ordinatively unsaturated aluminohydride adduct of tantalum(I)

T. J. McNeese, S. S. Wreford and B. M. Foxman, J. Chem. Soc., Chem. Commun., 1978, 500
DOI: 10.1039/C39780000500

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