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Issue 11, 1978
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X-Ray molecular structure and reactions of bis(styrene)bis(triphenylphosphine)ruthenium(0); the first sixteen-electron ruthenium(0) species

Abstract

The complex originally formulated as Ru-(styrene)(PPh3)3 has been shown by X-ray study to be Ru(styrene)2(PPh3)2, (containing solvent); the formation of dihydridotetrakis(triphenylphosphine)ruthenium(II), RuH2(PPh3)4, on interaction of the complex with hydrocarbons has been studied and the source of hydride attributed to triphenylphosphine.

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Article information


J. Chem. Soc., Chem. Commun., 1978, 463-464
Article type
Paper

X-Ray molecular structure and reactions of bis(styrene)bis(triphenylphosphine)ruthenium(0); the first sixteen-electron ruthenium(0) species

M. A. A. F. D. C. T. Carrondo, B. N. Chaudret, D. J. Cole-Hamilton, A. C. Skapski and G. Wilkinson, J. Chem. Soc., Chem. Commun., 1978, 463
DOI: 10.1039/C39780000463

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