Auto-oxidation–reduction of substituted nitrosobenzenes RC6H4NO (R = H, p-NMe2, p-OMe, p-Cl, m-NO2, and p-NO2) has been studied kinetically at 70–100° in cyclohexane solution. Experimental data and the influence of substituents are discussed on the basis of an equilibrium between monomer (M) and dimer (D), and of the reaction 2M → D being the rate-determining step.
I. R. Bellobono, P. L. Beltrame, B. Marcandalli, A. Fumagalli and M. Trinchieri, J. Chem. Soc., Perkin Trans. 2, 1977, 1989 DOI: 10.1039/P29770001989
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