Nitro-compounds were reduced to amines in high yields by using palladium, platinum, or rhodium metal catalyst with formic, phosphinic, or phosphorous acid. With formic acid, nitro-compounds containing fluorine were reduced but not those containing chlorine, bromine, or iodine. With the other acids, nitro-compounds containing any of the halogens were reduced with retention of the halogen.
I. D. Entwistle, A. E. Jackson, R. A. W. Johnstone and R. P. Telford, J. Chem. Soc., Perkin Trans. 1, 1977, 443 DOI: 10.1039/P19770000443
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