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Issue 3, 1977
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N. m. r. and infrared spectroscopic studies of hydrogen bonding in hindered alcohols. An instance of a true hydrogen bonded dimer in an alcohol

Abstract

Hydrogen bonding in the highly hindered alcohol 2,4-dimethyl-3-ethyl-3-pentanol has been studied by proton n.m.r. and infrared spectroscopy. This alcohol associates to form a dimer but no higher hydrogen bonded species; hence the monomer–dimer equilibrium can be studied without interference from competing processes. Spectral and thermodynamic properties for the hydrogen bonding are reported.

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J. Chem. Soc., Faraday Trans. 2, 1977,73, 438-442
Article type
Paper

N. m. r. and infrared spectroscopic studies of hydrogen bonding in hindered alcohols. An instance of a true hydrogen bonded dimer in an alcohol

E. D. Becker, E. E. Tucker and C. N. R. Rao, J. Chem. Soc., Faraday Trans. 2, 1977, 73, 438
DOI: 10.1039/F29777300438

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