Issue 12, 1977
From the journal:

Journal of the Chemical Society, Dalton Transactions

Alkyl-exchange reactions and their catalysis in platinum(II) complexes

Richard J. Puddephatt  and  Peter J. Thompson  

Abstract

A study of the symmetrisation reactions ot [PtR2L2] with [PtX2L2] to give [PtXRL2] has been made (R = Me, Ph, or C[triple bond, length half m-dash]CMe; L = PEt3, PMe3, PMe2Ph, or AsMe3; X = Cl, I, NCS, NO2, or NO3). The dependence of the reaction rate and stereochemistry on the substituents R, X, and L has been studied and the reaction mechanism is discussed. The reaction of cis-[PtCl2(PMe2Ph)2] with cis-[PtMe2(PMe2Ph)2] to give cis-[PtClMe(PMe2Ph)2] is catalysed by [Pt2Cl4(PMe2Ph)2], but the catalyst is destroyed in a competing reaction with cis-[PtMe2(PMe2Ph)2] to give cis-[Pt2(µ-Cl)2Me2(PMe2Ph)2].

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Article information

DOI
https://doi.org/10.1039/DT9770001219
Article type
Paper

J. Chem. Soc., Dalton Trans., 1977, 1219-1223

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Alkyl-exchange reactions and their catalysis in platinum(II) complexes

R. J. Puddephatt and P. J. Thompson, J. Chem. Soc., Dalton Trans., 1977, 1219 DOI: 10.1039/DT9770001219

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