Issue 7, 1977
From the journal:

Journal of the Chemical Society, Dalton Transactions

Spin cross-over and the Mössbauer emission spectrum of cobalt-57-labelled di-isothiocyanatobis(1,10-phenanthroline)-iron(II) and -cobalt(II)

Alfred G. Maddock  and  Jean J. Schleiffer  

Abstract

Mössbauer emission spectra of 57Co-labelled [Co(phen)2(NCS)2](phen = 1.10-phenanthroline) and 57Co-doped [Fe(phen)2(NCS)2] have been recorded at room temperature and at 77 and 4 K, and compared with the absorption spectrum of [Fe(phen)2(NCS)2]. A large proportion, sometimes >95%, of the emission corresponds to high-spin [57mFe(phen)2(NCS)2], irrespective of the temperature. However, both the absorption and emission spectra of [Fe(phen)2(NCS)2] vary in an unexplained manner with the method of preparation of the sample.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9770000617
Article type
Paper

J. Chem. Soc., Dalton Trans., 1977, 617-620

Permissions

Request permissions

Spin cross-over and the Mössbauer emission spectrum of cobalt-57-labelled di-isothiocyanatobis(1,10-phenanthroline)-iron(II) and -cobalt(II)

A. G. Maddock and J. J. Schleiffer, J. Chem. Soc., Dalton Trans., 1977, 617 DOI: 10.1039/DT9770000617

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements