Kinetics of the reduction of platinum(IV) by tin(II) and copper(I) in aqueous chloride solutions
Abstract
Rate constants for the PtIV+ SnII and the PtIV+ CuI redox reactions have been measured under various conditions using spectrophotometric and amperometric methods respectively. Rate equations (i) and (ii) describe the data for –d[PtIV]/dt=kobs.[PtIV][SnII](i),