A comparison is made between fully microscopic models of an ionic solution in a dipolar solvent, in which the solvent as well as the solute is treated on a molecular basis, and quasimacroscopic models, in which the solvent is treated as an ideal continuum. The central objects of inquiry are the molecular potentials of mean force, especially the ion-ion potential in the limit of infinite solute dilution.
J. S. Høye and G. Stell, Faraday Discuss. Chem. Soc., 1977, 64, 16 DOI: 10.1039/DC9776400016
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