The relative kinetic and thermodynamic factors controlling the Wagner–Meerwein inter-relationship of the perhydromethenocyclopenta[a]pentalenyl brosylates (1a) and (2a) have been determined; the endo-brosylate (7a) was also examined and found to be unusually reactive for an endo-2-norbornyl derivative.
M. A. Battiste, J. F. Timberlake, L. A. Paquette, C. R. Degenhardt, J. T. Martin, E. Hedaya, T. M. Su and S. Theodorpulos, J. Chem. Soc., Chem. Commun., 1977, 941 DOI: 10.1039/C39770000941
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