2,5-Dihydro-1,3,2-oxazaphosph(V)oles, prepared by reaction of 2-azido-oxirans with trico-ordinated phosphorus compounds, exhibit a trigonal bipyramidal structure with the sp2 nitrogen atom apical and the oxygen atom equatorial.
E. P. Kyba and D. C. Alexander, J. Chem. Soc., Chem. Commun., 1977, 934 DOI: 10.1039/C39770000934
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