Issue 24, 1977

Bridging acetylene complexes of nickel and platinum; X-ray crystal structure of [Pt3(Et3P)4(PhC2Ph)2]

Abstract

Di- and tri-platinum, and di-nickel acetylene complexes have been prepared, e.g.[Pt2{µ2(η2-PhC2Ph)}-(η2-PhC2Ph)(Ph3P)2], [Ni2{µ2(η2-Me3SiC2SiMe3)}(cod)2], and [Pt3{µ2(η2-PhC2Ph)}2(Et3P)4]; a single crystal X-ray diffraction study of the latter revealed a Pt·Pt·Pt sequence bridged transversely by two diphenylacetylene ligands.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 930-931

Bridging acetylene complexes of nickel and platinum; X-ray crystal structure of [Pt3(Et3P)4(PhC2Ph)2]

N. M. Boag, M. Green, J. A. K. Howard, J. L. Spencer, R. F. D. Stansfield, F. Gordon, A. Stone, M. D. O. Thomas, J. Vicente and P. Woodward, J. Chem. Soc., Chem. Commun., 1977, 930 DOI: 10.1039/C39770000930

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