Issue 23, 1977

A thermochemical cycle for the heat of complexing of Na+ and K+ cations with cryptand 222 in water and methanol

Abstract

Measurements of the enthalpy of transfer of cryptand 222 (I) and of the Na+ and K+ cryptates have been combined with heats of complex formation in water to yield by a thermochemical cycle the heats of complex formation in methanol.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 893-894

A thermochemical cycle for the heat of complexing of Na+ and K+ cations with cryptand 222 in water and methanol

M. H. Abraham, A. F. D. de Namor and W. H. Lee, J. Chem. Soc., Chem. Commun., 1977, 893 DOI: 10.1039/C39770000893

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