Issue 22, 1977

X-Ray crystal and molecular structure of µ-carbonylbis-µ-(bisdiphenylarsinomethane)-dichlorodipalladium(I); a binuclear compound of palladium(I) without a Pd–Pd bond

Abstract

The crystal structure of [Pd(dam)Cl]2CO (dam = Ph2AsCH2AsPh2) shows that the palladium atoms are not directly bonded or halogen bridged but that they are spin-paired via an unusual bridging carbonyl group.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 823-824

X-Ray crystal and molecular structure of µ-carbonylbis-µ-(bisdiphenylarsinomethane)-dichlorodipalladium(I); a binuclear compound of palladium(I) without a Pd–Pd bond

R. Colton, M. J. McCormick and C. D. Pannan, J. Chem. Soc., Chem. Commun., 1977, 823 DOI: 10.1039/C39770000823

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