The allylanion (4) derived from allyltrimethylsilane reacts with carbonyl compounds to give δ-hydroxyvinylsilanes which can be readily converted into γ-lactols and γ-lactones.
D. Ayalon-Chass, E. Ehlinger and P. Magnus, J. Chem. Soc., Chem. Commun., 1977, 772 DOI: 10.1039/C39770000772
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