1,5-Diazabicyclo[3.3.3]undecane (1a) and 1,6-diazabicyclo[4.3.3]dodecane (1b) have been synthesized by reductive cleavage of the hydrazinium dications (3a) and (3b); a preliminary account of the properties of these species and the intermediate radical cations (2a) and (2b) is given.
R. W. Alder, R. B. Sessions, J. M. Mellor and M. F. Rawlins, J. Chem. Soc., Chem. Commun., 1977, 747 DOI: 10.1039/C39770000747
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